Clayfen
WebClayfen has been shown to be an efficient ring nitrating agent for a wide variety of phenols and nitrogen heterocyclic compounds 14 but no side chain nitration has been demonstrated.
Clayfen
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WebDec 1, 2024 · In the first 20 min, the adsorbance of MB onto NiFe 2 O 4 nanorods rapidly rose from 34.80% to 96.12%, and then gradually decreased over time until the equilibrium of adsorption-desorption ... WebMar 1, 1997 · The amount of clayfen used in our reactions is half of that used by earlier workers 7 under heterogeneous conditions that employs large excess of hydrocarbon …
WebApr 9, 1993 · In particular the clayfen has become an effective oxidizing catalyst for the oxidation of alcohols 6 and cleavage of C=N bond . In the course of our studies in the application of clay in organic synthesis, herein we wish to report the oxidative cleavage of thiol acetate into disulphides with clay supported ferric nitrate in the absence of solvent. WebJonathan Clayden. Jonathan Clayden and his research group work on the construction of molecules with defined shapes, and are particular interested in exploring and exploiting …
WebDec 1, 1998 · DOI: 10.1080/00397919808004475 Corpus ID: 93953967; CLAY SUPPORTED AMMONIUM NITRATE CLAYAN : A RAPID AND CONVENIENT REGENERATION OF CARBONYLS IN DRY MEDIA @article{Meshram1998CLAYSA, title={CLAY SUPPORTED AMMONIUM NITRATE CLAYAN : A RAPID AND … WebClayfen, produced from ferric nitrate and montmorillonite, is used for the oxidation of thiols to disulfide, and alcohols to aldehydes. Ferric nitrate is useful for regio- and stereo-selective nitration of various aromatic, aliphatic, and heteroaromatic olefins. This reaction provides nitroolefins with excellent E-selectivity.
WebApr 14, 1997 · Thio acetals and ketals derived from aldehydes and ketones are readily deprotected by clayfen within seconds under solvent-free conditions. This rapid and …
WebMar 24, 1997 · Adsorbed on clayfen, alcohols are readily oxidized to carbonyl compounds upon exposure to microwaves under solvent-free conditions. This rapid, selective and … how many people are in north carolinaWebJan 3, 2024 · Ultrasound promoted nitration of phenol and substituted phenols using ferric nitrate and Clayfen respectively in the ionic liquid ethyl ammonium nitrate has exhibited significant enhancement in rates of reaction as well as high para selectivity as compared to corresponding reactions performed withou … how many people are in nyuWebJun 4, 1998 · A facile solvent-free synthesis of β-nitrostyrenes is described from styrene and its substituted derivatives using inexpensive ‘doped’ clay reagents, clayfen and clayan. … how can i be rich without workingWebJan 1, 2012 · “Clayfen”, a reactive form of ferric nitrate stabilized by adsorption unto an acidic K 10 clay, is an efficient and selective nitrating agent of phenols, under very mild conditions. It leads ... how can i be rich in two daysWebFeb 1, 2003 · Ultrasound promoted nitration of phenol and substituted phenols using ferric nitrate and Clayfen respectively in the ionic liquid ethyl ammonium nitrate has exhibited significant enhancement in ... how can i be rich fastWebApr 15, 2001 · Clayfen is unstable , prone to vigorous or slow exothermic decomposition, together with evolution of NO 2 gas. Careful observance of the preparation procedure 1 is critical (in particular, T <50 °C and a crust on the glassware at the flaking‐off stage). Never store in gas‐tight containers, nor in contact with strongly reducing material ... how many people are in panic at the discoWebSep 1, 2010 · “Clayfen”, a reactive form of ferric nitrate stabilized by adsorption unto an acidic K 10 clay, is an efficient and selective nitrating agent of phenols, under very mild conditions. It leads specifically to mononitration, with high regioselectivities. These characteristics, coupled with its low cost, ease of preparation and the simplicity of … how can i be rich in uk